the formal charges should match the electronegativity of the atom, that is negative charges should be on the more electronegative atoms and positive charges on the least electronegative atoms if possible.formal charges of 0 for as many of the atoms in a structure as possible. the fewest number of formal charges possible, i.e.No Lewis structure is complete without the formal charges. The formal charge is calculated by: (group number of atom) - (½ number of bonding electrons) - (number of lone pair electrons), i.e. Now you need to determine the FORMAL CHARGES for all of the atoms.In this case the N is short 2 electrons so we can use a lone pair from the left most O atom to form a double bond and complete the octet on the N atom. If you have run out of electrons you are required to use lone pairs of electrons from a terminal atom to complete the octet on the central atom by forming multiple bond(s). If there are remaining electrons they can be used to complete the octet of the central atom.Add lone pairs of electrons on the terminal atoms until their octet is complete or you run out of electrons. Of the 24 valence electrons available in NO 3 -, 6 were used to make the skeletal structure. Now we need to add lone pairs of electrons.This usually means the atom lower and/or to the right in the Periodic Table, N in this case. The central atom will be the one that can form the greatest number of bonds and/or expand its octet. Draw a skeletal structure for the molecule which connects all atoms using only single bonds.This will be the sum of the group number a of all atoms plus the charge. First determine the total number of valence electrons in the molecule.The following is an example of how to draw the "best" Lewis structure for NO 3 - (learning by example).
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